Product ID:PN:P06400 N-HEXANE (PURE GRADE) (SEE SUPPLEMENTAL)
MSDS Date:01/01/1987
FSC:6665
NIIN:01-303-4938
Kit Part:Y
MSDS Number: CDZYQ

PHILLIPS 66 COMPANY

758 ADAMS BLDG
BARTLESVILLE, OK 74004
US

Emergency Phone: 918-661-3865/8118

Info Phone: 918-661-8327/714-864-2310

Cage: 46935

PHILLIPS PETROLEUM CO

BARTLESVILLE, OK 74004 US

Telephone: 800-234-6603

Cage: 46935

A/B ARE MSDS

RTECS: 9999999ZZ

HEXANE (N-HEXANE) (CERCLA)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 99.4%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9596

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHYLCYCLOPENTANE

CAS: 96-37-7

RTECS: GY4640000

Fraction By Weight: 0.4%

3-METHYL PENTANE

CAS: 96-14-0

RTECS: SA2995500

Fraction By Weight: 0.1%

2,4-DIMETHYLPENTANE

CAS: 108-08-7

Fraction By Weight: 0.1%

LD50 LC50 Mixture:ORAL, RAT LD50 >5G/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:MAY CAUSE MILD IRRIT.SKIN:MAY
CAUSE MILD IRRIT.CAN BE ABSORBE THRU SKIN IN HARMFUL AMTS.INHAL:VAP
MAY BE MILDLY IRRIT OT LUNGS.OVEREXPO MAY RESULT IN
DIZZ,HEAD,EXCITATION,CNS DEPRESS.INGEST:MAY CA USE EFFECTS SIMILAR
TO INHAL,GI IRRIT.MAY BE ASPIRATED RESULTING IN INFLAMM,POSSIBLE
FLUID ACCUMULATION IN LUNGS.
Explanation of Carcinogenicity:PER MSDS:KNOWN CARC/SUSPECT CANC:NO.
Effects of Overexposure:CHRONIC HIGH LEVEL N-HEXANE EXPO DMG THE
NERVOUS SYSTEM INITIALLY PRODUCING LACK OF FEELING IN THE
EXTREMITIES & POSSIBLY PROGRESSING TO MORE SEVERE NERVE
DAMAGE.INHAL OF HI LEVELS(1000,5000PPM)OF N-H EXANE HAS PRODUCED
TESTICULAR DMG IN RATS.MICE EXPO TO SAME DOSE LEVELS SHOED NO
TESTICULAR EFFECTS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
TARGET ORGAN TOXIN:NERVE TOXIN,LUNG-ASPIRATION HAZARD BOTH IN
HUMAN/ANIMAL.

First Aid:EYE:FLUSH W/RUNNING WATER FOR @LEAST 15MINS.IRRIT/ADVERSE
SYMPT DVLP GET MED ATTN.SKIN:WASH W/SOAP/WATER.IRRIT/ADVERSE SYMPT
DVLP GET MED ATTN.INHAL:REMOVE FROM EXPO.DIFFI BREATH GIVE
OXY;BREATH CEASE S ADMIN ART RES FOLLOWED BY OXY.GET IMMED MED
ATTN.INGEST:DONT INDUCE VOMIT.GET IMMED MED ATTN.DR:GASTRIC LAVAGE
USING CUFFED ENDOTRACHEAL TUBE MAY BE PERFORMED @YOUR DISCRETION.

Flash Point Method:TCC
Flash Point:-10F,-23C
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:1.2
Upper Limits:7.7
Extinguishing Media:DRY CHEMICAL,FOAM,CARBON DIOXIDE (CO2).
Fire Fighting Procedures:EVACUATE AREA OF ALL UNNECESSARY PEOPLE.USE
NIOSH/MSHA APPROV SCBA,OTHER PROT EQPMT/GARMETS IF EXPO CONDITIONS
WARRANT.SHUT OFF SOURCE.COOL EXPO CNTNR/(SUPPLE)
Unusual Fire/Explosion Hazard:CARBON OXIDES FORM WHEN BURN.HIGHLY FLAMM
VAP-HEAVIER THAN AIR MAY ACCUMULATE IN LOW AREAS &/OR SPREAD ALONG
GROUND AWAY FROM HNDLG SITE.FLASHBK ALONG VAP TRAIL

Spill Release Procedures:EVACUATE AREA OF ALL UNNECESSARY PEOPLE.WEAR
PROT EPQTM/GARMENTS IF EXPO CONDITIONS WARRANT.SHUT OFF
SOURCE/CONTAIN SPILL.PROTECT FROMING.KEEP OUT OF
H2OSOURCES/SEWERS.ABSORB IN DRY INERT MATL(SAND,EA RTH,ETC).TRANSF
TO DIPO DR W/NON-SPARK EQPMT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DONT GET IN EYE/SKIN/CLOTH.DONT BREATH
VAP/MIST/FUME/DUST.DONT INGEST.MAY BE ASPIRATED INTO LUNGS.WEAR
PROT EQPMT/GARMENTS IF EXPO CONDITIONS WARRANT.
Other Precautions:USE ONLY W/ADEQU VENTI.KEEP AWAY FROM
HEAT/SPAKR/FLAME.STORE IN WELL-VENTI AREA.STORE IN TIGHTLY CLOSD
CNTNR.BOND/GROUND DURING TRANSF.CONTACT IMMED SUPERVIOSR FOR SPEC
INSTRUCTIONS BEF WORK ON CONTAM IN EQPMT INITIATED.WEAR PPE AS
WARRANT.

Respiratory Protection:NOT GENERALLY REQUIRED.FOR CONCEN EXCEEDING
RECOMMENDED EXPO LEVEL USE NIOSH/MSHA APPROVED AIR PURIFYING
RESPIRATOR.
Ventilation:USE ADEQUATE VENTI TO CONTROL EXPOSURE BELOW RECOMMENDED
LEVELS.
Protective Gloves:NEOPRENE,VITON
Eye Protection:SAF GLASSES W/SIDE SHIELD,FACESHIELD,GOG
Other Protective Equipment:AVOID UNNECESSARY SKIN CONTAM W/MATLS.WHERE
SPEC/UNUSUAL USE/CONDITONS EXIST SEEK EXPERT ASSIST OF INDUST
HYG/QUAL PROF.
Work Hygienic Practices:WASH THOROUGHLY AFT HNDLG.LAUNDER CONTAM CLOTH
BEF REUSE.
Supplemental Safety and Health
NSN ITEM IS HEXANE IN AIR HOWEVER VENDOR:AERIFORM INSTRUMENTS SUBMITTED
2 MSDS-HEXANE FROM PHILLIPS 66 & AIR FROM LIQUID AIR CORP(SEE
PNIND:B);EACH MSDS ENTERED INDIVIDUALLY.HCC FOR NSN ITEM NOT HEXAN
E. FIREFIGHT:EQPMT W/H2OFOG/SPRAY.DONT SPRAY H2O DIR ON FIRE-PROD
FLOAT,COULD REIGN ON H2O SURFACE.

HCC:G3
Boiling Pt:B.P. Text:152F,67C
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:2.5PSIG
Vapor Density:3
Spec Gravity:0.664
pH:NP
Viscosity:0.4CST @100F
Evaporation Rate & Reference:0.3, BUTYL ACETATE=1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUID,MILD ODOR
Percent Volatiles by Volume:100
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
OXYGEN AND STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:CARBON OXIDES FORMED WHEN BURNED.

Waste Disposal Methods:(INSURE CONFORMITY W/ALL APPLICABLE DISPO
REGS)INCINERATE OR PALCE IN PERMITTED WASTE MANAGEMENT
FACILITY.RCRA:D001 IGNITABLE.PRIOR TO DISPO CONSULT ENVIR CONTACT
TO DETERMINE IF TCLP REQUIRED.40CFR26 1.SUBJ TO SARA 313/40CFR372.

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